Diaquabis(3-chlorobenzoato-?O)bis(nicotinamide-?N 1)cobalt(II)
dc.contributor.author | Bozkurt, Nihat | |
dc.contributor.author | Özcelik, Nefise Dilek | |
dc.contributor.author | Çaylak Delibaş, Nagihan | |
dc.contributor.author | Necefo?lu, Hacali | |
dc.contributor.author | Hökelek, Tuncer | |
dc.date.accessioned | 13.07.201910:50:10 | |
dc.date.accessioned | 2019-07-16T08:22:59Z | |
dc.date.available | 13.07.201910:50:10 | |
dc.date.available | 2019-07-16T08:22:59Z | |
dc.date.issued | 2013 | |
dc.department | Sabire Yazıcı Fen-Edebiyat Fakültesi | |
dc.description.abstract | In the title complex, [Co(C7H4ClO2) 2(C6H6N2O)2(H 2O)2], the CoII atom is located on an inversion center and is coordinated by two 3-chlorobenzoate (CB) anions, two nicotinamide (NA) ligands and two water molecules. The four O atoms in the equatorial plane form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxylate group and the adjacent benzene ring is 9.14 (9)°, while the pyridine and benzene rings are oriented at a dihedral angle of 82.18 (8)°. In the crystal, N - H?O and O - H?O hydrogen bonds link the molecules into a two-dimensional network lying parallel to (101). ?-? stacking between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.7765 (8) Å] further stabilizes the crystal structure. © Bozkurt et al. 2013. | |
dc.identifier.doi | 10.1107/S160053681301458X | |
dc.identifier.endpage | m350 | en_US |
dc.identifier.issn | 1600-5368 | |
dc.identifier.issue | 6 | en_US |
dc.identifier.scopusquality | N/A | |
dc.identifier.startpage | m349 | en_US |
dc.identifier.uri | https://dx.doi.org/10.1107/S160053681301458X | |
dc.identifier.uri | https://hdl.handle.net/20.500.12451/2682 | |
dc.identifier.volume | 69 | en_US |
dc.indekslendigikaynak | Scopus | |
dc.language.iso | en | |
dc.relation.ispartof | Acta Crystallographica Section E: Structure Reports Online | |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
dc.rights | info:eu-repo/semantics/closedAccess | |
dc.title | Diaquabis(3-chlorobenzoato-?O)bis(nicotinamide-?N 1)cobalt(II) | |
dc.type | Article |