Browsing by Author "Ramakrishnan, Raghunathan"

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Reduction of 2-H-substituted pyrrolinium cations: the carbon-carbon single bond in air stable 2,2′-bipyrrolidines as a two-electron-source

Nayak, Mithilesh Kumar; Elvers, Benedict J.; Mandal, Debdeep; Das, Ayan; Ramakrishnan, Raghunathan; Mote, Kaustubh R.; Schulzke, Carola; Yıldız, Cem Burak; Jana, Anukul (Royal Society of Chemistry, 2023)

Reduction of 2-H-substituted pyrrolinium cations via initially formed secondary radicals results in either dimerisation or H-abstracted products, while the outcome depends on the N-substituents. The resultant central ...