Mahata, AlokChrysochos, NikolasKrummenacher, IvoChandra, S.Braunschweig, H.Schulzke, C.Sarkar, B.Yıldız, Cem BurakJana, A.2021-11-092021-11-0920210022-3263https:/dx.doi.org/10.1021/acs.joc.1c01120https://hdl.handle.net/20.500.12451/8610Herein, we report the synthesis, characterization, and reactivity of ?,??-diamino-p-tetrafluoroquinodimethane, a p-tetrafluorophenylene-bridged monosubstituted carbene-based Thiele's hydrocarbon A. The compound exhibits a reversible two-step one-electron oxidation with a marginally stable radical cation state B. The in situ formation of the radical cation could be confirmed by electron paramagnetic resonance spectroscopy.eninfo:eu-repo/semantics/embargoedAccess?,??-Diamino- p-tetrafluoroquinodimethane?,??-diamino- p-tetrafluoroquinodimethane: stability of one- and two-electron oxidized species and fixation of molecular oxygenArticle8615104671047310.1021/acs.joc.1c0112034269573Q2WOS:000684025500043Q1