Baran, TalatSargın, İdrisMenteş, AyferKaya, Murat13.07.20192019-07-2913.07.20192019-07-2920160926-860X1873-3875https://doi.org/10.1016/j.apcata.2016.05.012https://hdl.handle.net/20.500.12451/5594To be industrially feasible, and applicable in synthesis of fine chemicals, a catalyst has to possess high turnover number (TON) and turnover frequency (TOF). In this study, a new cross-linked chitosan derivative was synthesized by using 2,2'-pyridil as a cross-linking agent. 2,2'-Pyridil cross-linked chitosan was used to as a support material for palladium catalyst. Chitosan-pyridil-based Pd(II) catalyst was tested in the microwave-assisted synthesis of biaryls via Suzuki coupling reactions. The catalyst yielded remarkable TONs of up to 20,000 and TOFs of up to 240,964 by using very low catalyst loading (5 x 10(-3)% mol) in a short reaction time (5 min). The catalyst also showed a better recyclability. (C) 2016 Elsevier B.V. All rights reserved.eninfo:eu-repo/semantics/closedAccessSuzuki CouplingPyridilCross-LinkingTONTOFArticle523122010.1016/j.apcata.2016.05.012Q1WOS:000381593700002N/A