Nayak, Mithilesh KumarElvers, Benedict J.Mandal, DebdeepDas, AyanRamakrishnan, RaghunathanMote, Kaustubh R.Schulzke, CarolaYıldız, Cem BurakJana, Anukul2023-10-042023-10-0420231359-7345https:/dx.doi.org10.1039/d3cc00891fhttps://hdl.handle.net/20.500.12451/11061Reduction of 2-H-substituted pyrrolinium cations via initially formed secondary radicals results in either dimerisation or H-abstracted products, while the outcome depends on the N-substituents. The resultant central carbon-carbon single bond in the dimerised 2,2?-bipyrrolidine derivatives can be oxidised chemically and electrochemically. The notably air and moisture-stable dimers were subsequently utilised as a source of two electrons in various chemical transformations.eninfo:eu-repo/semantics/closedAccessReduction of 2-H-substituted PyrroliniumArticle59446698670110.1039/d3cc00891f37183853Q1WOS:000987702700001Q2